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Helical Arrangement of Interstrand Stacked Pyrenes in a DNA Framework

✍ Scribed by Vladimir L. Malinovskii; Florent Samain; Robert Häner

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
242 KB
Volume
46
Category
Article
ISSN
0044-8249

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A self-organizing system composed of two oligopyrene strands that leads to the formation of an interstrand helical stack embedded in a double strand of DNA is reported by R. Häner and co-workers in their Communication on page 4464 ff. Fluorescence and CD spectroscopy show that helical organization t

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## Abstract Benzo[__a__]pyrene diol epoxide (BPDE) was reacted __in vitro__ with (2'‐deoxy)nucleotides and with calf thymus DNA. The modified DNA was enzymatically hydrolyzed to the 5'‐monophosphate nucleotides using deoxyribonuclease I (DNA‐ase I), nuclease P1 and snake venom phosphodiesterase (SV