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He(I) photoelectron and uv/visible absorption spectra of N3−, NO2− and NO3− in solution

✍ Scribed by R.E. Ballard; Jimmy Jones; Elizabeth Sutherland; Chun Bae Lee

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
540 KB
Volume
97
Category
Article
ISSN
0009-2614

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✦ Synopsis

The Ht<I) photoelectron spectra ha%e been measured of tetra-N-butyhmmonium salts of N;. NOS snd SO< in ad+nitrile solution; there are peaks or shoulders for Nj at 6.9 cV (lQ_', for NO; at 7.0 eV (6~1)~' and 5.6 cV (Ibz)-I. and for NO; at =S.O eV (la;)-' 3s N; + N-methylpyridiniuiuh and x9.0 eV. Also measured are energies of electron-transfer processes in solution. such -N3 + N-methylpyridinium. _41ulysis of the results enables rhe distinction to be mAde between electron transfer and internal transitions. e.g. the near UV absorption bands of N; in solution. of controversial sssignment. XC undoubtedly due to electron transfix to solvent.

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