1,4-Diphosphabutadiyne: A Realistic Targ
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F. Matthias Bickelhaupt; Friedrich Bickelhaupt
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Article
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1999
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John Wiley and Sons
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English
⚖ 333 KB
To assess the viability of 1,4diphosphabutadiyne (PCCP, 2 a) as a target for synthesis, we have investigated C 2 P 2 isomers 2, the end-on complexes [Cr(CO) 5 PCCP] (3) and [(CO) 5 Cr-(PCCP)Cr(CO) 5 ] (4), as well as their side-on analogues 6 and 7, respectively, using nonlocal density functional th