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Heavy-atom effects on metalloporphyrins and polyhalogenated porphyrins

✍ Scribed by Emı́lia G. Azenha; Arménio C. Serra; Marta Pineiro; Mariette M. Pereira; J. Seixas de Melo; Luis G. Arnaut; Sebastião J. Formosinho; A.M.d'A. Rocha Gonsalves

Book ID
108429292
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
441 KB
Volume
280
Category
Article
ISSN
0301-0104

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Suhstituent effects an complex formation between variously substituted metallodeuteroporphyrins with filled 12~ orbitals and extraplanar hgand(s) ean be correlated by Hammett freeenergy plots. The slopes of these plots are positive and the correlation is high with substituent constants typical of re