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Heavy atom effects on geminate and free radical recombination

✍ Scribed by Koichi Kikuchi; Masato Hoshi; Etsuko Abe; Hiroshi Kokubun


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
495 KB
Volume
45
Category
Article
ISSN
1010-6030

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At 77 K, 1,2,3+tetrahydroquinoline (THQ) forms a simple hydrogen bond with ethanol while at 300 K, a hydrogen-bonded ion pair is formed. Both intermolecular intersystem crossing and intramolecular singlet-triplet energy-transfer processes induced by heavy-atomquencher dihalobenzenes are weak in etha