Heavy Atom Effect on the Charge Recombination Dynamics of Photogenerated Geminate Ion Pairs
โ Scribed by Nicolet, Olivier; Vauthey, Eric
- Book ID
- 126460016
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 166 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
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The recombination kinetics of geminate electron-cation pairs in liquid hexane depends on the photoionization wavelength used for charge pair creation. Pairs generated by two-photon ionization of anthracene with 355 nm light exhibit a first half-life for recombination of 108 ps at 191 K; 266 nm light