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Heats of solution of gaseous anilinium and pyridinium ions in water and intrinsic basicities in aqueous solution

โœ Scribed by Taft, R. W.; Taagepera, M.; Summerhays, K. D.; Mitsky, J.


Book ID
124085328
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
274 KB
Volume
95
Category
Article
ISSN
0002-7863

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Relative basicities of carboxylate lone
โœ Julianto Pranata ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 549 KB

## Abstract Relative basicities of the lone pairs of the acetate ion have been determined using __ab initio__ calculations for the gas phase and Monte Carlo simulations for the aqueous phase. The syn lone pair is found to be more basic by only 1.25 __pK__~__a__~ units. This small difference is the