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Heats of hydrogenation. X. Conjugative interaction in cyclic dienes and trienes

✍ Scribed by Turner, Richard B.; Mallon, Barbara J.; Tichy, M.; Doering, W. V. E.; Roth, W. R.; Schroeder, G.

Book ID
121407304
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
786 KB
Volume
95
Category
Article
ISSN
0002-7863

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## Abstract 1,3‐Cyclohexadiene, 1,3‐cycloheptadiene and cycloheptatriene are smoothly hydrogenated to cyclohexene and cycloheptene, respectively, when heated to 260–340Β°C with an excess of 9,10‐dihydroanthracene (DHA) in diphenyl ether or benzonitrile. On the basis of a mechanistic study a nonchain