Heats of formation of binary transition metal alloys
✍ Scribed by A. Pasturel; P. Hicter; F. Cyrot-Lackmann
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 144 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0038-1098
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A method is described for determining the heats of formation of highly stable metal silicides and data are given for the following compounds:-Ti& TiSi, TiSiz, Zr&, ZrSi, ZrSiz, ThSiz, V&i, Ta&, TaSi,, MoSiz, and WSi2. The highest heats of formation are those of compounds containing Group IVa metals
FIG. 2. Alliage 3,5% vieilli 600 h B. 400°C apr& trempe. intense correspond au reseau de la matrice, peu d6form6, les trois autses aux trois positions possibles du pritcipite sur les plans (100). La tache la plus Bloignee sit&e dans la direction du centre correspond au plan (110) parallele a la dir
## Heats of formation have been measured by liquid tin solution calorimetry for a complete series of Au-Cu alloys in equilibrium states at 720°K and for the same alloys at 320°K after rapid quenching from 873°K. The asymmetry in the heat of formation curve at 720°K is in accord with observations