To elucidate the mechanism af the mass transfer at a gas evolving electrode, the thickness of the diffusion layer 6 has been determined as a function of the volume rate of the gas evolution u, for both hydrogen and oxygen evolving electrodes in alkaline solution. The effect of electrode material, al
Heat transfer at gas evolving electrodes
โ Scribed by Helmut Vogt
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 383 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0013-4686
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โฆ Synopsis
The outlines of an available concept for heat transfer at gas evolving electrodes (Z&e-Magrini) are discussed. A new method for prediction of heat transfer on the basis of the analogy between heat and mass transfer is derived from known theoretical equations and tested in comparison to experimental data of various workers. NOMENCLATURE thermal ditTusivity (m2/s) electrode area (m*) geometric factor (-) deoarture diameter Cm) ditfusion coefficient (I&/S) acceleration of gravity (m/s') temperature (Kj gas volume flow rate (m"/s) number of bubbles (-) heat transfer coefficient (W/m' K) mass transfer coefficient (m/s) coefficient of thermat expansion (K-I) density (kg/m3) dynamic viscosity (kg/m s) fractional surface coverage (-) thermal conductivity (W/m K) kinematic viscosity (m*/s) gas hold.up (-) -Nu = ad/i Nusselt number Pr = v/a Prandtl Re = V&/Av Reynolds number SC = v/D
๐ SIMILAR VOLUMES
The effect of H2 and O2 evolution on the mass transfer coefficiem of the reduction of K3Fe(CN)6 and the oxidation of &Fe(CN), at nickel electrodes was studied up to 105 mA/cm2. The relation between the rate of gas evolution and the mass transfer coefficient was found to be: and log K = a + 0.25 log
## Absirac-Mass transfer at gas evolving electrodes with add&i&al major hydrodynamic liquid Row is influenced by two phenomena: effects directly resulting from the generated bubbles and effects by high liquid velocity parallel to the electrode surface. For the case of superposition of both mechani