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Heat of Formation of Oleums from Sulfur Trioxide and Water

✍ Scribed by Herrmann, Carl V.

Book ID
127141249
Publisher
American Chemical Society
Year
1941
Weight
264 KB
Volume
33
Category
Article
ISSN
0019-7866

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πŸ“œ SIMILAR VOLUMES

Direct formation of cyclic sulfates util
Direct formation of cyclic sulfates utilising hypervalent iodine species and sulfur trioxide adducts
✍ Richard I. Robinson; Simon Woodward πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 83 KB

PhIO reacts with SO 3 β€’DMF at 0Β°C to form an active sulfating reagent; subsequent addition of alkenes results in the direct formation of cyclic sulfates in moderate to good yield (35-75%). Terminal, 1,1-disubstituted and cyclopentenes participate in the reaction which is technically very straightfor