Heat of formation for sec-butyl cation in the gas phase
โ Scribed by John C. Traeger
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 244 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
In the gas phase, (CH 3 ) 3 SiOSi Y (CH 3 ) 2 and (CH 3 )CH 2 SiOSi Y (CH 3 ) 2 ions 1 and 2 were formed in the external source of a Fourier transform ion cyclofrom resonance (FT-ICR) spectrometer by electron impact ionization of (CH 3 ) 3 SiOSi(CH 3 ) 3 . In the FT-ICR cell, the electrophilic cente
The gas phase iodination of cyclobutane was studied spectrophotometrically in a The early stage of the reaction static system over the temperature range 589" to 662ยฐK. was found to correspond to the general mechanism where the Arrenius parameters describing kl are given by log kl/M-' sec-' = 1 1.
## Abstract A method for estimating the heats of formation of gaseous, open chain cations via a suitable isodesmic substitution is reported.