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Heat of dilution of electrolyte solutions. Experimental method and data analysis

✍ Scribed by J. Barthel; J. Kröner

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
567 KB
Volume
81
Category
Article
ISSN
0167-7322

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✦ Synopsis

We report on heat of dilution measurements with a calorimeter of the heat conduction type in flow mode and twin construction developed in our laboratory for high precision measurements. Measuring method and data analysis are exemplified with measurements on aqueous solutions. Special interest is devoted to the extrapolation of heat of dilution measurements to infinite dilution. The results of chemical model (CM) calculations and mean spherical approximation (MSA) are compared with the experimental data.

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