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Heat of adsorption of CO on Pt(1 1 1) obtained by sum frequency generation vibrational spectroscopy—a new technique to measure adsorption isotherms

✍ Scribed by Staffan Westerberg; Chen Wang; Gabor A. Somorjai


Book ID
108279089
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
168 KB
Volume
582
Category
Article
ISSN
0039-6028

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Structural change of CO adsorbed on Pt(1
✍ Satoshi Katano; Shinsaku Dobashi; Jun Kubota; Ken Onda; Akihide Wada; Satoru S. 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 213 KB

The IR-visible sum-frequency generation (IVSFG) method was used to perform time-resolved vibrational measurements of CO/Pt(1 1 1). Irradiation of intense picosecond laser pulses (35 ps, 1064 nm) resulted in a drop in intensity, redshift, and broadening of the on-top CO stretching peak, followed by r