Heat-loss corrections for small isoperibol-calorimeter reaction vessels
β Scribed by L.D Hansen; T.E Jensen; S Mayne; D.J Eatough; R.M Izatt; J.J Christensen
- Book ID
- 103146010
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 542 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The problem of adequately correcting thermal titration curves for heat losses in isoperibolic microcalorimeters during rapid reactions in small volumes has been examined. With a dataβacquisition system for the simultaneous encoding of changes in heat, pH, and time linked directly to a D
A hybrid of isoperibol and phase-change bomb calorimeters with gallium as melting body was developed. This calorimeter allows one to raise the temperature of the reagents in the bomb to about 1100 K during (45 to 50) min. The procedure of calibration of the calorimetric system is described; the mola