The presence of the diffusion-limited gel or Trommsdorff effect in free-radical polymerizations poses a challenge for the modeling of these reactors. The available models cannot be applied to industrial reactors because of their inability to account for nonisothermal effects and semibatch operations
โฆ LIBER โฆ
Heat effects for free-radical polymerization in glass ampoule reactors
โ Scribed by S. Zhu; A.E. Hamielec
- Book ID
- 107846400
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 444 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0032-3861
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For the first time, modelling of the binary copolymerization rate is presented as a function of the solvent quality. This modelling was performed using a set of constant parameters only, i.e. with exclusion of variables. As an example, the copolymerization rate of the comonomer system methylmethacry