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Heat effects and the mechanism of inelastic deformation of organic glassy polymers

✍ Scribed by O. B. Salamatina; S. I. Nazarenko; S. N. Rudnev; É. F. Oleinik


Publisher
Springer US
Year
1989
Tongue
English
Weight
444 KB
Volume
24
Category
Article
ISSN
1573-8922

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Heat effects in sorption of organic vapo
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During supposedly isothermal sorption/desorption of gases or vapors by solid polymers, latent heat effects alter local temperatures with the result that diffusion behavior may appear to be non-Fickian. Even when sorption curves are seemingly Fickian, spurious values of the diffusion coefficient, D,