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Heat capacity of LiInS2, LiInSe2 and LiInTe2 between 200 and 550 K

✍ Scribed by Prof. Dr. G. Kühn; E. Pirl; Dr. H. Neumann; Dr. E. Nowak


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
279 KB
Volume
22
Category
Article
ISSN
0232-1300

No coin nor oath required. For personal study only.

✦ Synopsis


and LiInTez between 200 and 550 H The molar heat capacity at constant pressure of LiInS,, LiInSe, and LiTnTe, was measured in the temperature range from about 200 K to 550 K. An analysis of t'he experimental data showed that the anharmonic contribution to the heat capacity can be described by a polynomial of fourth order in the temperat'ure. A comparison of the results for the Li InC;[ compounds with those for the AgR"' C;I and A*lR1'-C: chalcopyrite compounds showed that the lattice anharmonicity effects are essentially influenced by the specific nature of the Li-Cvl bond. I )ie molare Wiirmekapazitat bei konstantem Druck wurde fur LiInS,, LiInSe, und LilnTe, im I'emperaturbereich von et,wa 200 I ( bis 550 K gemessen. Eine Analyse der experimentellen Uaten zeigte, da13 der anharmonische Reitrag zur Wiirmekapazitat durch ein Polynom vierten Grades in der Temperatur beschrieben werden kann. Ein Vergleich der Ergebnissc fur die LiInCrI-Verbindungen mit den Resultaten fur die AgB' I' C;'iind A"RI'C;-Verbindungen mit Chalkopyritstruktur zeigt, da13 die durch Gitteranharmonizit a t bedingten Effekto wesentlich durch die spezifische Natur der Li-Cvl-Bindung beein-flu13t werden.


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