## Dedicated to Professor Hermann NEELS on the occasion of his 75th birthday The molar heat capacity a t constant pressure of Ag,Ge,,P,, is measured in the temperature range from 180 t o 550 K and the standard molar enthalpies and entropies relative t o 298.15 K are calculated on the basis of thes
Heat capacity of copper tellurates(IV) at temperatures from 350 K to 550 K
β Scribed by G.G. Gospodinov
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 71 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
β¦ Synopsis
The temperature dependences of the molar heat capacities of (\mathrm{CuTeO}{3}, \mathrm{CuTe}{2} \mathrm{O}{5}), and (\mathrm{CuO} \cdot \mathrm{CuTeO}{3}) were determined. By statistical manipulation of the values obtained, the parameters in the equations for the corresponding compounds were determined using the leastsquares method: (C_{p, \mathrm{~m}}=a+b(T / \mathrm{K})+c(T / \mathrm{K})^{-2}). These equations and the standard molar entropies were used to determine (\Delta_{0}^{T} S_{m}^{\circ}, \Delta_{T}^{T} H_{m}^{\circ}), and (\left(\Phi_{\mathrm{m}}^{\circ}+\Delta_{0}^{T} H_{m}^{\circ} / T\right)) for (T=298.15 \mathrm{~K}).
π SIMILAR VOLUMES
Thermodynamic properties of sodium borosilicate glasses {56.7 SiO 2 , (43.7 -x) B 2 O 3 , xNa 2 O} where x = 14.4, 22.9, and 32.5, have been studied. The heat capacity was measured using an adiabatic calorimeter at temperatures between 13 K and 300 K. The thermodynamic functions were calculated from
Heat capacities of PbI , ZnCl , and AsI have been determined by adiabatic shield 2 2 3 calorimetry from T s 5 K to T s 350 K. No anomalous regions were found in the heat capacity of PbI and ZnCl . Two anomalous regions were found in the heat capacity of AsI : 2 2 3 one small sharp peak at T s 161 K,
The heat capacity of manganese monophosphide MnP has been determined by adiabatic shield calorimetry at temperatures from 5 K to 840 K. The heli-to ferromagnetic transition is noted only as a slightly enhanced heat capacity at T f 53 K. A -type heat capacity contribution with maximum at T s 289.5 K