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Heat capacity in the range 13–300 K and phase transitions of ferrocene-d10

✍ Scribed by Yutaka Shiomi; Michio Sorai

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
352 KB
Volume
95
Category
Article
ISSN
0009-2614

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✦ Synopsis

The hiSh-temperature (HT) phase of Fe(CsDs)z is easily undercooled to exhibit a A-type phase transition at 164.1 K in the matastabb state. The stable loo-t~mpe~t~e (LT) phase is obtained by anneaiing the undercooled BT phase around 190 i;. A first-order phase transition characterized by a superheating effect occurs at 251 K between the stable LT and HT phases. A comparison with Fe(CsHs)z has been made.

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✍ Kazuhisa Kobashi; Masaharu Oguni 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 502 KB

Heat capacities of chlorocyclohexane (CAS[542-18-7]), c-CHCL(CH2)5, and bromocyclohexane, (CAS[108-85-0]), c-CHBr(CH2)5, were measured with adiabatic calorimeters in the temperature range between T=8 K and T=300 K and the standard thermodynamic functions were evaluated. For chlorocyclohexane, temper