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Heat capacity and thermodynamic behaviour of Mn3O4 and ZnMn2O4 at low temperatures

✍ Scribed by K. Chhor; J.F. Bocquet; C. Pommier; B. Chardon

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
631 KB
Volume
18
Category
Article
ISSN
0021-9614

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✍ A.L. Barra; Andrea Caneschi; Dante Gatteschi; David P. Goldberg; Roberta Sessoli πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 134 KB

The high-5eld EPR spectra of a mixed valence cluster compound of formula [Et 3 NH] 2 [Mn(CH 3 CN) 4 (H 2 O) 2 ] [Mn 10 O 4 (biphen) 4 Br 12 ] con5rm that the high-spin ground state (S ‫؍‬ 12) of the cluster has a negative zero-5eld splitting, D β€«ΨŠΨβ€¬ 0.037(1) cm ؊1 . The reversal of the magnetization