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Heat capacities and thermodynamic properties of Ni9(btz)12(DMA)6(NO3)6

✍ Scribed by Yi-Xi Zhou, Li-Xian Sun, Zhong Cao, Fen Xu, Chun-Hong Jiang, Cheng-Li Jiao, Hui Zhang, Jian Zhang, Huai-Ying Zhou, Fen Li, Zi-Ming Zhao, Huang-Zhi Zhang

Book ID
118256481
Publisher
Springer Netherlands
Year
2012
Tongue
English
Weight
292 KB
Volume
111
Category
Article
ISSN
0022-5215

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Two stable solid phases with composition in the range from ( 45 to 48 ) moles per cent of \(\mathrm{S}\) exist for (nickel + sulfur): \(\mathrm{Ni}_{9} \mathrm{~S}_{8}\) which disproportionates to \(\mathrm{Ni}_{1-\delta} \mathrm{S}\) and \(\mathrm{Ni}_{7_{ \pm}} \mathrm{S}_{6}\) above \(T=\) \((709