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Head-to-head vinyl polymers. XI. Preparation and characterization of poly(methyl acrylate) and poly(methyl methacrylate) consisting of head-to-head and head-to-tail units through cyclopolymerization of acrylic and methacrylic anhydrides

✍ Scribed by Ohya, Takahiro ;Otsu, Takayuki

Publisher
John Wiley and Sons
Year
1983
Weight
590 KB
Volume
21
Category
Article
ISSN
0360-6376

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## Abstract Head‐to‐head (H–H) and head‐to‐tail (H–T) poly(methyl acrylate)s (PMAs) were hydrolyzed in a mixture of acetone and water (4:1 by volume) at 30°C by using various alkali hydroxides as catalysts. For comparison, the H–T copolymer with 26% H–H units, dimethyl succinate (DMS), dimethyl glu

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## Abstract Head‐to‐head (H–H) poly(allyl alcohol) (PAA) was prepared by the LiAlH~4~ reduction of H–H poly(methyl acrylate) obtained from the methylation of alternating copolymer of ethylene with maleic anhydride. H–H poly(allyl acetate) (PAAc) and H–H poly(allyl benzoate) (PABz) were further deri