H/D isotopic effect on the hydrogen bond between tertiary amines and alcohols
✍ Scribed by Jürgen Mendel; Angelika Mögel; Alfred Kolbe
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 328 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0167-7322
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
2%~ diffcrcncc in chemicnt shift between hydrogen bonded protons and deutcrons has been cxzmincd bodr tlworetitally nnd cxpcrimcntaliy. it is shown that valuable information about the hydrogen bond poteM can bc cxtmcted from this isotope effect on chcmicd rhifts.
The influence of an Li\* ion on the structure and bonding of the H-bond interaction of an N-aromatic heterocycle and a singly bonded N-amine is studied by ab initio SCF calculations with imidazole (Imh) and NH, serving as models of the two families. Full optimization of structures have been carried