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H/D exchange between H2–D2O and D2–H2O catalyzed by water soluble tertiary phosphine complexes of ruthenium(II) and rhodium(I)

✍ Scribed by Gábor Kovács; Levente Nádasdi; Ferenc Joó; Gábor Laurenczy


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
223 KB
Volume
3
Category
Article
ISSN
1387-1609

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✍ Satoru Yamaguchi; Satoshi Kudoh; Yoko Kawai; Yoshiki Okada; Takaaki Orii; Kazuo 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 213 KB

Collisional reactions of size-and energy-selected unprotonated water clusters (H 2 O) þ n (n ¼ 2 and 3) in a singlecollision with D 2 O were investigated at very low collision energy ranging from 0.05 to 2.0 eV using guided-ion beam tandem mass spectrometry. First, in the unimolecular and collision-