Harmonic polynomials, hyperspherical harmonics, and atomic spectra
โ Scribed by John Scales Avery
- Book ID
- 104006674
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 618 KB
- Volume
- 233
- Category
- Article
- ISSN
- 0377-0427
No coin nor oath required. For personal study only.
โฆ Synopsis
The properties of monomials, homogeneous polynomials and harmonic polynomials in d-dimensional spaces are discussed. The properties are shown to lead to formulas for the canonical decomposition of homogeneous polynomials and formulas for harmonic projection. Many important properties of spherical harmonics, Gegenbauer polynomials and hyperspherical harmonics follow from these formulas. Harmonic projection also provides alternative ways of treating angular momentum and generalised angular momentum. Several powerful theorems for angular integration and hyperangular integration can be derived in this way. These purely mathematical considerations have important physical applications because hyperspherical harmonics are related to Coulomb Sturmians through the Fock projection, and because both Sturmians and generalised Sturmians have shown themselves to be extremely useful in the quantum theory of atoms and molecules.
๐ SIMILAR VOLUMES
A method proposed earlier by Aguilera, Moshinsky, and Kramer, for adapting a system of translationally invariant four-particle harmonic oscillator functions to the symmetry of the permutation group S(4), is applied to hyperspherical harmonic functions depending on three relative vectors. Except for
## Abstract A general formula for angular integrations in manyโdimensional spaces (derived in a previous paper) is applied to several problems connected with solution of the Schrรถdinger equation for manyโparticle systems. Matrix elements of the Hamiltonian are derived for cases where the potential