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Harmonic polynomials, hyperspherical harmonics, and atomic spectra

โœ Scribed by John Scales Avery


Book ID
104006674
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
618 KB
Volume
233
Category
Article
ISSN
0377-0427

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โœฆ Synopsis


The properties of monomials, homogeneous polynomials and harmonic polynomials in d-dimensional spaces are discussed. The properties are shown to lead to formulas for the canonical decomposition of homogeneous polynomials and formulas for harmonic projection. Many important properties of spherical harmonics, Gegenbauer polynomials and hyperspherical harmonics follow from these formulas. Harmonic projection also provides alternative ways of treating angular momentum and generalised angular momentum. Several powerful theorems for angular integration and hyperangular integration can be derived in this way. These purely mathematical considerations have important physical applications because hyperspherical harmonics are related to Coulomb Sturmians through the Fock projection, and because both Sturmians and generalised Sturmians have shown themselves to be extremely useful in the quantum theory of atoms and molecules.


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## Abstract A general formula for angular integrations in manyโ€dimensional spaces (derived in a previous paper) is applied to several problems connected with solution of the Schrรถdinger equation for manyโ€particle systems. Matrix elements of the Hamiltonian are derived for cases where the potential