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Hardness Profile and Activation Hardness for Rotational Isomerization Processes. 2. The Maximum Hardness Principle

✍ Scribed by Cardenas-Jiron, Gloria I.; Toro-Labbe, Alejandro


Book ID
120187682
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
787 KB
Volume
99
Category
Article
ISSN
0022-3654

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The maximum hardness principle is examined within the Gyftopoulos-Hatsopoulos three-level model for an electronic system. As an atom or a molecule approaches equilibrium at some chemical potential /z and constant temperature T, its softness (inverse hardness) is shown to most often approach a minimu