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Hamiltonian dynamics of simple chemical reactions

✍ Scribed by T. Georgian; J. M. Halpin; G. L. Findley

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
566 KB
Volume
26
Category
Article
ISSN
0020-7608

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πŸ“œ SIMILAR VOLUMES

Hamiltonian dynamics of chemical reactio
Hamiltonian dynamics of chemical reactions. Consecutive first-order reactions and reactions possessing one autocatalytic intermediate
✍ T. Georgian; J. M. Halpin; G. L. Findley πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 618 KB

is applied to all consecutive first-order, single-step reactions, and to all reactions possessing one autocatalytic intermediate. The reaction Hamiltonians presented are shown to be consistent with the phenomenological rate equations and the relationship between reaction form and the form of the rea

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By an application of the K.A.M. theory, we derive an accurate normal form valid in the vicinity of partially hyperbolic tori which arise close to simple resonances in nearly integrable Hamiltonian systems. This normal form allows to detect orbits homoclinic to a persistent torus. Moreover, it also g