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HALOGENATION. XV. DIRECT IODINATION OF HYDROCARBONS BY MEANS OF IODINE AND NITRIC ACID.

โœ Scribed by Datta, Rasik Lal; Chatterjee, Nihar Ranjan


Book ID
120436047
Publisher
American Chemical Society
Year
1917
Tongue
English
Weight
486 KB
Volume
39
Category
Article
ISSN
0002-7863

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Selective functionalisation of hydrocarb
โœ Francesco Minisci; Francesco Recupero; Cristian Gambarotti; Carlo Punta; Roberto ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 145 KB

Alkylbenzenes are selectively functionalised to the corresponding acetates by nitric aerobic oxidation catalysed by N-hydroxyphthalimide and iodine. With cyclohexane the oxidation leads to a mixture of cyclohexyl acetate and trans-2-iodocyclohexyl acetate. The mechanism is discussed.