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Halogen Complexes. II. The Types and Mean Lifetimes of Complexes Formed by Iodine and 2,4,6-Trimethylpyridine

โœ Scribed by Larsen, David Walter; Allred, A. L.


Book ID
126804219
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
762 KB
Volume
87
Category
Article
ISSN
0002-7863

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The reactions of [Fe2(ฮท-Cp)2(CNAr)4] com
โœ A. R. Manning; Paul J. A. Soye; Patrick A. McArdle; Desmond Cunningham ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Springer ๐ŸŒ English โš– 783 KB

complexes with halogens Summary [Fe2(q-Cp)2(CNAr)4 ] (2) (CNAr=Ph, C6H4Me-2, C6H4Et-2, C6H3Me2-2,4, C6HaMe2-2,6, C6H3(Me)Et-2,6, C6H3Et2-2,6 or C6H3i-Pr2-2,6 ) react with I2 to give [Fe(q-Cp)(CNAr)2I], but with Br 2 [Fe(q-Cp) (CNAr)3 ] + salts are the only products; IBr gives a mixture of the two.