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Halogen-catalyzed pyridine N-oxide oxidation of isonitriles to isocyanates

✍ Scribed by Johnson, Harry William; Krutzsch, Henry C.

Book ID
127020382
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
444 KB
Volume
32
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Catalyzed Rearrangement of Nitrile Oxide
Catalyzed Rearrangement of Nitrile Oxides to Isocyanates
✍ Dipl.-Chem. Georg Trickes; Prof. Dr. Herbert Meier πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 116 KB

**The simultaneous migration of two ligands** makes the rearrangement of nitrile oxides __(1)__ to isocyanates __(2)__ one of the most interesting ones in organic chemistry. However, use of the thermal reaction __(1)__ is severely limited by competing dimerization. The rearrangement proceeds in exce