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H3PMo12O40 as a new and reusable catalyst for Mukaiyama and Mannich reactions in heterogeneous media

โœ Scribed by Akbar Heydari; Samad Khaksar; Mehdi Sheykhan; Mahmoud Tajbakhsh


Book ID
103834914
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
279 KB
Volume
287
Category
Article
ISSN
1381-1169

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โœฆ Synopsis


In the presence of a catalytic amount of H 3 PMo 12 O 40 (2 mol%) ketene silyl acetal react with aldehydes or imines (generated in situ from aldehydes and amines) to yield the corresponding coupling products in good yield.


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An efficient and improved procedure for oxidative cleavage of C N bond is developed in the presence of H 6 PMo 9 V 3 O 40 as a green and reusable catalyst in refluxing acetic acid.