(H3N(CH2)6NH3)4 [W18P2O62] · 3H2O, a Microporous Solid from Dawson Anions and 1,6-Diaminohexane
✍ Scribed by Dipl.-Chem. Markus Hölscher; Dr. Bodo Zibrowius; Prof. Wolfgang F. Hölderich; Dr. Ulli Englert
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 458 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0044-8249
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N-sulfinylacylamides R-C(ϭO)-NϭSϭO react with (CF 3 ) 2 BNMe 2 (1) to form, by [2ϩ4] cycloaddition, six-membered rings cyclo-(CF 3 ) 2 B-NMe 2 -S(ϭO)-NϭC(R)-O for R ϭ Me (2), t-Bu (3), C 6 H 5 (4), and p-CH 3 C 6 H 4 (5) while N-sulfinylcarbamic acid esters R-O-C(ϭO)-NϭSϭO react with 1 to yield mixt
Red crystals of [H 3 O ´(dibenzo-18-crown-6)][Te 2 Br 9 ] (1) were isolated from a solution of TeBr 4 and dibenzo-18crown-6 in CH 3 CN containing a small amount of hydrobromic acid. The compound crystallizes in the triclinic space group P 1 with the cell dimensions a = 9.010(2), b = 13.403(3), c = 1