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H2O− or NO2−3 in Y-type zeolites

✍ Scribed by Martyn C.R. Symons; D.Robert Brown; Jacques C. Vedrine


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
132 KB
Volume
52
Category
Article
ISSN
0009-2614

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✦ Synopsis


The assignnrent of ,UI CSR triplet, detected in +rradintcd Y-type zcolites. to 1120 ic; discussed, ,uld it IS ~ugg~btcd th,~l NO:-ir a better al;signment.


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ESR study of H2O− radicals trapped in Y-
✍ Antoine Abou-Kaïs; Jacques C. Vedrine 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 304 KB

A new ESR signal has been observed in y-irradiated Y-type zeolite, the Naf ions of which have been exchanged by divalent cations such as Mgzf or Ca\*+. Its ESR parameters are as follows: gt = 2.0065,ga = 2.0060 andgs = 2.0021 k 0.0002 and Ct = 41. C2 = 42.5 and C3 = 73 + 0.5 Oe for hlgY samples andg

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Green single crystals of PrCl 2 (NO 3 ) ´5 H 2 O have been obtained from an aqueous solution of PrCl 3 and Pr(NO 3 ) 3 . The crystal structure [monoclinic, P2/c, Z = 4, a = 1228.8(3), b = 648.4(1), c = 1266.0(4) pm, b = 91.91(3)°] contains cationic and anionic Pr 3+ complexes according to [PrCl 2 (H