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[H2CZrH2]: The Simplest Carbene Hydride Complex, Agostic Bonding, and CH Activation of CH4 to Form [(CH3)2ZrH2]

✍ Scribed by Lester Andrews; Han-Gook Cho; Xuefeng Wang


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
169 KB
Volume
117
Category
Article
ISSN
0044-8249

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Reversible CH Bond Activation Reactions
✍ Mark J. Chilvers; Rodolphe F. R. Jazzar; Mary F. Mahon; Michael K. Whittlesey 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 2 views

## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy