We have observed the rotational levels in the v ϭ 2, 3, 5, 6, 7, and 8 vibrational manifolds of the 2 1 ⌬ g state of 7 Li 2 via the A 1 ⌺ u ϩ intermediate levels by ⌬⌳ ϭ 2 transitions. This violation of the ⌬⌳ ϭ 0, Ϯ1 selection rule is due to the interaction with the G 1 ⌸ g state. Band-by-band depe
H2+ Wavefunctions and the Lennard-Jones-Brillouin-Wigner procedure for the determination of the Π and Δ states of Li2+ and LiH+
✍ Scribed by B. Joulakian
- Book ID
- 103024282
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 334 KB
- Volume
- 143
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The eigenvalues and eigenfunctions of Hz are used to obtain wavefunctions for the Il and A states of Liz and LiH+ through the Lennard-Jones-Brillouin-Wigner perturbation procedure using a model potential for Li +. The method is simpler than the variational procedure and provides results of good accuracy.
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