H-D exchange and hydrogen spillover in the Pd/SiO2; system: Kinetics and detection of hydrogen atoms
β Scribed by E. Baumgarten; C. Lentes-Wagner; R. Wagner
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 767 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
A model based on the two film approximation is proposed for the description of the kinetics of the hydrogen isotope exchange between CHCl3 and DzO. In this model, details of mass transfer in interfacial region between the two liquid phases are considered and the kinetics of the exchange reaction is
The energies of several configurations of the CHg radical (including those of D3h, C4v, and C sym- mctry) have been cnlculntcd with the CNnO/Z method. Low energy paths for unexpcctcd stcrco-c 2 . emlcnl processes. which moy hc important in the reactions of "hot" tritium atoms. are predicted Co exis