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H+ addition to the heteroatomic CoP3 cluster. Synthesis of the radical CoP3+ cluster and electrochemical study

โœ Scribed by Massimo Di Vaira; Piero Stoppioni; Stefano Midollini; Franco Laschi; Piero Zanello


Book ID
108429037
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
623 KB
Volume
10
Category
Article
ISSN
0277-5387

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Generation, Characterization, and Electr
โœ Cyril Cugnet; Dominique Lucas; Edmond Collange; Bernard Hanquet; Alain Vallat; Y ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 502 KB

## Abstract Addition of formate on the dicationic cluster [Pd~3~(dppm)~3~(ฮผ~3~โ€CO)]^2+^ (dppm=bis(diphenylphosphinomethane) affords quantitatively the hydride cluster [Pd~3~(dppm)~3~(ฮผ~3~โ€CO)(ฮผ~3~โ€H)]^+^. This new palladiumโ€“hydride cluster has been characterised by ^1^H NMR, ^31^P NMR and UV/Vis sp