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Guest Binding and New Self-Assembly of Bisporphyrins

✍ Scribed by Haino, Takeharu; Fujii, Takashi; Fukazawa, Yoshimasa


Book ID
120267980
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
407 KB
Volume
71
Category
Article
ISSN
0022-3263

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DABCO-Directed Self-Assembly of Bisporph
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## Abstract Three isomeric zinc bisporphyrins have been prepared by covalently linking together two aminoporphyrins with an isophthalic acid derivative. The porphyrins differ in the substitution pattern on the __meso__ phenyl groups, that is, __ortho__, __meta__, or __para__. Titrations carried out

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Self-assembled Pd(II) complexes derived from a chiral bidentate ligand 1 and (en)Pd(NO3) 2 (2) in D20 showed concentration dependent and guest-induced reorganization behaviour.