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Guanidinium group acts as effective CH acceptor (π-donor) in the CH/π hydrogen bond: a database study

✍ Scribed by Umezawa, Yoji; Nishio, Motohiro

Book ID
121291831
Publisher
Taylor and Francis Group
Year
2013
Tongue
English
Weight
256 KB
Volume
25
Category
Article
ISSN
1061-0278

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The Aromatic CH/π Hydrogen Bond as an Important Factor in Determining the Relative Stability of Diastereomeric Salts Relevant to Enantiomeric Resolution − A Crystallographic Database Study
✍ Hiroko Suezawa; Shinji Ishihara; Yoji Umezawa; Sei Tsuboyama; Motohiro Nishio 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 201 KB

## Abstract A systematic study was carried out to understand the principle underlying the process of enantiomeric resolution by the use of the Cambridge Structural Database. The crystal structures of fourteen pairs of diastereomeric salts, containing the mandelate anion, or its analogues, as the ch