## Abstract KDP crystals were rapidly grown from solution doped with different Ba^2+^ concentrations. The effects of Ba^2+^ on the growth rate, morphology and quality of KDP crystals were discussed. Significant changes in shapes and volume of the grown crystals have been observed. During the growth
Growth and high frequency dielectric study of pure and thiourea doped KDP crystals
β Scribed by S. S. Hussaini; N. R. Dhumane; G. Rabbani; P. Karmuse; V. G. Dongre; M. D. Shirsat
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 168 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0232-1300
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β¦ Synopsis
Abstract
Non linear optical (NLO) materials have acquired new significance with the advent of a large number of devices utilizing solidβstate laser sources. Several NLO materials have been used for this kind of technological applications. The Potassium diβhydrogen phosphate (KDP) one of NLO material having superior non linear optical properties has been exploited for variety of applications. In the present investigation we have grown KDP crystals from aqous solution with thiourea, an organic non linear optical material. We could enhance the SHG efficiency of thiourea doped KDP crystal. It was 1.99 times more that of pure KDP. We observed more enhancements in nonlinearity for low concentration of thiourea.The crystal structure and cell parameters of grown crystal were determined from Powder XRD.The incorporation of thiourea in the grown crystals was qualitatively analyzed from FTβIR study. The absorption spectra of pure and thiourea doped KDP crystal reveal that thiourea doped KDP crystals would be a better nonlinear optical (NLO) material for second harmonic generation (SHG) than pure KDP. The thermal decomposition and weight loss of pure and thiourea doped KDP crystal was observed by thermogravimetric (TGA) analysis and Differential Scanning Calorimetry (DSC). The high frequency dielectric study of pure KDP crystal, thiourea doped KDP crystals and organic additive thiourea was carried out using Xβband at frequency 8GHZ and 12GHZ by transmission line wave guide method. We observed low dielectric constant of thiourea doped KDP crystal when it is doped with 2mole% of thiourea. (Β© 2007 WILEYβVCH Verlag GmbH & Co. KGaA, Weinheim)
π SIMILAR VOLUMES
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