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Growth and characterization of a new langasite-type single crystal Sr3NbAl1.5Ga1.5Si2O14

✍ Scribed by Yiming Zeng; Yanqing Zheng; Haikuan Kong; Jun Xin; Hui Chen; Xiaoniu Tu; Pan Gao; Erwei Shi

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
119 KB
Volume
46
Category
Article
ISSN
0232-1300

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A new compound, Bi 3.5 V 1.2 O 8.25 (25.53 mol% V 2 O 5 ), has been found in the system Bi 2 O 3 +V 2 O 5 . It crystallizes in the triclinic symmetry with a ‫؍‬ 16.452(1) A > , b ‫؍‬ 16.886(1) A > , c ‫؍‬ 7.0914(7) A > , ‫؍‬ 91.330(8)3, ‫؍‬ 95.186(9)3, ‫؍‬ 96.031(9)3, and Z ‫؍‬ 10. The structure is

Single-crystal growth and characterizati
Single-crystal growth and characterization of mullite-type orthorhombic Bi2M4O9 (M = Al3+, Ga3+, Fe3+)
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Pure and homogeneous single crystals of orthorhombic mullite-type Bi 2 M 4 O 9 (M = Al 3+ , Ga 3+ , Fe 3+ ), and a mixed Bi 2 Fe 1.7 Ga 2.3 O 9 crystal from an equimolar Ga/Fe composition were grown by the top seeded solution growth (TSSG) method. All these compounds melt incongruently in the range