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Group theoretical methods for determining permitted terms of the electronic states of complexes in crystals. III. The use of plethysm for classification of the permitted terms of impurity complexes in crystal

✍ Scribed by B. A. Men; V. L. Cherepanov; A. N. Men


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
223 KB
Volume
7
Category
Article
ISSN
0020-7608

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✦ Synopsis


Abstract

A procedure for the use of the plethysm operation for classification of the permitted electronic terms of impurity complexes in a crystal is presented. The cases of polyatomic symmetrical complexes are discussed as examples.


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An effective Hamiltonian for calculating rotational energy levels of an open-shell diatomic molecule, in a 2Sϩ1 ⌺ electronic state, weakly bonded to a closed-shell partner was presented (W. M. Fawzy, J. Mol. Spectrosc. 191, 68 -80 (1998)). The Hamiltonian was given as H ϭ H ev ϩ H rot ϩ H sr ϩ H ss