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Group IVB organometallic compounds of furan: 13C, 29Si and 119Sn n.m.r. Spectra

✍ Scribed by M. Mägi; E. Lippmaa; E. Lukevics; N. P. Erĉak

Publisher: John Wiley and Sons
Year: 1977
Tongue: English
Weight: 324 KB
Volume: 9
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270090510

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✦ Synopsis

Abstract

The ^13^C, ^29^Si and ^119^Sn chemical shifts of 2‐ and 2,5‐substituted organometallic (M=C, Si, Ge, Sn, Pb) derivatives of furan were measured. The most important factors, determining the specific features of the studied spectra, are d‐orbital availability and atomic radius of the central atom M, as well as the relatively higher (as compared with benzene) energies of the π‐electron energy levels of the furan ring.

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