Group 13 Chemistry I
Managing Editor
Editorial Board
Volume Editors
Structure and Bonding Also Available Electronically
Preface
Contents
Contents of Volume 104
Group 13 Chemistry II Biological Aspects of Aluminum
Contents of Volume 105 (preliminary)
Group 13 Chemistry III Industrial and Applied
Structure and Bonding in Boron-Containing Macrocycles and Cages - Comparison to Related Structures with Other Elements Including Organic Molecules
Introduction
Boron Compounds with Macrocyclic Structures
Calixarene-Type Macrocycles
Introduction
Borazine Derivatives
3-(Diethylboryl)pyridines and (3-Aminophenyl)boronic Acid Derivatives
Porphyrinogen and Porphyrin-Type Macrocycles
Introduction
Triazolyl- and Imidazolylboranes
Boron-Bridged Tetrathiaporphyrinogens
Porphyrin-Type Macrocycles
Crown Ether-Type Macrocycles
Introduction
(Acyloxy)boranes
(Acylamino)boranes
(Phosphinoyloxy)-, (Phosphorylamino)-, (Sulfonyloxy)- and (Seleninoyloxy)boranes
Cyclophane-Type Macrocycles
Introduction
Borates and Boronates from Bidentate Ligands
Borates and Boronates from Tridentate Ligands
Boron Compounds with Cage-Like Structures
Borate Cages
Borasiloxane Cages
Borophosphonate Cages
Vanadium Borate and Borophosphate Cluster Anions
Application of Boron-Containing Hosts in Ionic and Molecular Recognition
Metal Complexes with Boron-Containing Hosts
Boron-Containing Pseudocryptates
Borylated Bis(dioxime)metal Complexes and Related Compounds
Introduction
Complexes of the M(dioxime-BR2)2 and M(dioxime-BR2)2L Type
Complexes of the RCo(dioxime-BR2)2L and Fe(dioxime-BR2)2LL' Type
Complexes of the M(LBR2)X Type
Other Related Compounds
Borylated Tris(dioxime)metal Complexes and Related Compounds
Complexes of the M[RB(dioxime)3BR] Type
Other Related Compounds
Molecular Recognition by Boronic Acid Derivatives
Molecular Recognition by Monoboronic Acid Derivatives
Molecular Recognition by Diboronic Acid Derivatives
Conclusions and Perspectives
References
Multiple Bonding Between Heavier Group 13 Elements
Introduction
Bonding in the Neutral Dimers RMMR (M = Al, Ga, In, Tl, R = H, alkyl or aryl) and the Neutral Radicals RMMR2 [M = Al or Ga, R = Si(f-Bu)3]
Multiple M-M Bonds via Reduction of R2MMR2 Species [M = Al, Ga; R = C6H2-2,4,6-i-Pr3 (Trip) or -CH(SiMe3)2] and R2MMR' [M = Al, Ga; R = Si(f-Bu)3] to Monoanions
Heavier Group 13 M-M Multiple Bonding in Reduced Metal Cluster Species
Bonding in the Compound Na2Ga2(C6H3-2,6-Trip2)2
Future Work
References
The R2M+ Group 13 Organometallic Fragment Chelated by P-Centered Ligands
Introduction
Scope of the Chapter
Catalysis and the Ligand Effect
Organometallic Derivatives of Group 13 Elements Al, Ga, In or Tl
With Phosphanes
Primary, Secondary and Tertiary Phosphanes
Diphosphanes
With Phosphorous-Nitrogen Ligands
Pyridyl Phosphanes
Imino and Amino Phosphanes
Cyclic Phosphazenes and Phosphazanes
Cyclotriphosphazenes
Cyclodiphosphazanes
Acyclic Phosphazenes and Phosphazanes
Conclusions
References
Synthesis, Structure and Reactivity of Group 13/15 Compounds Containing the Heavier Elements of Group 15, Sb and Bi
Introduction
Lewis Acid-Base Adducts
Adducts of the Type R3M-ER'3 - General Trends
Synthesis of Group 13-Stibine and -Bismuthine Adducts
Temperature-Dependent NMR Investigations
Single Crystal X-Ray Structure Determinations
Computational Calculations
Bisadducts of the Type [R3M]2[E2R'4]
Syntheses and Solid State Structures of Group 13-Distibine and -Dibismuthine Bisadducts
Heterocycles of the Type [R2MER'2]X
General Synthetic Pathways
Single Crystal X-Ray Structure Analyses
Reactivity of Heterocycles
Synthesis of Lewis Base-Stabilized Monomers of the Type Base-M(R2)ER'2
Solid State Structures - General Trends
Transition Metal Complexesb of Lewis Base-Stabilized Monomers
Conclusions
References
Author Index Volumes 101-103
Subject Index