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Ground State Properties of the A -site Ordered Manganites, R BaMn 2 O 6 ( R = La, Pr and Nd)

✍ Scribed by Nakajima, Tomohiko; Kageyama, Hiroshi; Yoshizawa, Hideki; Ohoyama, Kenji; Ueda, Yutaka


Book ID
120008671
Publisher
Institute of Pure and Applied Physics
Year
2003
Tongue
English
Weight
629 KB
Volume
72
Category
Article
ISSN
0031-9015

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The crystal structure of R 2 Mo 6 O 21 Á H 2 O consists of two [Mo 2 O 7 ] 2Γ€ -containing layers (A and B layers) and two interstitial R(1) 3+ and R(2) 3+ cations. Each [Mo 2 O 7 ] 2Γ€ group is composed of two corner-sharing [MoO 4 ] tetrahedra. The [Mo 2 O 7 ] 2Γ€ in the B layer exhibits a disorder t