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Griseofulvin biosynthesis: New evidence of two acetate-dispositions in the ring a from 13C nuclear magnetic resonance studies

โœ Scribed by Yoshihiro Sato; Taiko Oda; Shiro Urano

Book ID
108381968
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
247 KB
Volume
17
Category
Article
ISSN
0040-4039

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Studies on ergochrome biosynthesis with "C-labelled acetate'\*' and 14C-and 'H-labelled emodin (2)2,3 are consistent with the pathway octaketide (1) + anthraquinone (2) + benzophenone carboxylic ester (3) + tetrahydroxanthone (4) + ergochrome (e.g. !a-4a), but do not exclude dimerization of ,2 or so