Grignard Preparation of Fluorene-2-Carboxylic Acid 1
✍ Scribed by Morrison, D. C.
- Book ID
- 127302375
- Publisher
- American Chemical Society
- Year
- 1952
- Tongue
- English
- Weight
- 316 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.046 wR factor = 0.118 Data-to-parameter ratio = 8.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Pictet-Spengler condensation of dopamine with (+)-menthyl pyruvate afforded a diastereomeric mixture of menthyl salsolinol-l-carboxylate, from which pure diastereomer was isolated by repeated recrystallizations in ca. 20% yield. Acid hydrolysis of the menthyl ester furnished (-)-(R)-salsolinol-l-car