✦ LIBER ✦

Graphical Abstract: Eur. J. Org. Chem. 4/2006

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 223 KB
Volume: 2006
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200690009

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✦ Synopsis

The cover picture shows that thiolate-bridged diruthenium complexes promote intermolecular and intramolecular propargylation of aromatic compounds with propargylic alcohols to give the corresponding propargylated aromatic compounds in high yields with complete selectivity. The reaction is considered to be an electrophilic substitution of the aromatic compounds by the ruthenium-stabilized propargyl cation. Details are described in the article by Y. Nishibayashi et al. on p. 881 ff.

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