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The cover picture shows an artistic impression of the interaction of different types of 3‐hydroxypiperidine‐containing natural products with an imaginary receptor protein. The 3‐hydroxypiperidine motif represents a privileged structural element that occurs in a large variety of biologically relevant compounds displaying a range of activities. Examples include the natural products 3‐hydroxypipecolic acid, prosopinine, morusimic acid D, cassine and febrifugine. Enantioselective synthetic strategies to these compounds are presented in the Microreview by F. P. J. T. Rutjes et al. on p. 2831 ff. Cover picture design by Dr. Sander S. van Berkel.
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## Abstract **The cover picture shows** a panel of functional __N__‐salicylidene derivatives that can be rationally designed and assembled by crystal engineering. The amplitude of their thermochromism and/or photochromism can be finely tuned as shown by the central needle. This study is supported b